Search results for "Spectroscopie Raman"
showing 3 items of 3 documents
New methods for the determination of local residual stresses
2022
Splat solidification in thermal sprayed coatings relies on phenomena of various origins, time constants, and dimensional scales which altogether lead to complex residual stress states. As a result, in-service performance may be under or overestimated. Hence, this work aims at characterizing residual stress fields using high resolution instruments: a Raman spectrometer and a tailor-made Near-Field Scanning Microwave Microscope (NFSMM). Investigation areas are of 1 µm and 0.020 µm diameter respectively, both techniques are non-destructive and rely on electromagnetic interaction with matter.A preliminary study was conducted on sintered trigonal Cr2O3 with NFSMM as the technique is used for the…
Study of the dynamics of biomolecules by high speed atomic force microscopy and surface enhanced Raman spectroscopy
2015
This thesis focuses on the coupling of High–Speed Atomic Force Microscopy (HS-AFM) and Surface Enhanced Raman Spectroscopy (SERS) for biomolecule analysis. We have designed a fabrication protocol to manufacture “SERS-active” substrates. The efficacy of gold, silver and gold-silver bimetallic crystalline nanoparticle substrates were evaluated. We have investigated the impact of optical and morphological features of the substrates on Raman signal intensity by analyzing well-known samples such as bipyridine ethylene and methylene blue molecules. We took an interest in three distinct biological problematics with HS-AFM and SERS analyses. First, we have detected the chemical signature of cytochr…
Syntheses of TiO2 anatase nanocrystals with controlled size distribution. Influence of the crystallites size on the Raman spectrum and investigation …
2006
The determination of the size and the size distribution of anatase TiO2 nanopowders using Raman spectroscopy is presented. Several synthesis methods (soft chemistry, water-in-oil microemulsion, continuous hydrothermal synthesis) are used in order to control the size (from 3 to 20 nm), shape, phase and size distribution. The shift and width of the anatase Eg peak are often used to obtain the nanoparticles size. Homever, this peak is also sensitive to nonstoichiometry and others parameters. Low-frequency Raman scattering does not suffer from this problem. Size distibutions obtained by Raman spectroscopy and MET micrographs are compared. Finally, in situ Raman spectroscopy is used to study the…